Publikation:

CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes : Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis

Vorschaubild

Dateien

Moenkeberg_239601.pdf
Moenkeberg_239601.pdfGröße: 535.89 KBDownloads: 368

Datum

1989

Autor:innen

Mönkeberg, Sigrid
van Raaij, Edith
Kiesele, Herbert

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-239601
DOI (zitierfähiger Link)
https://doi.org/10.1016/0022-328X(89)87027-5
ArXiv-ID

Internationale Patentnummer

Link zur Lizenz
Urheberrechtlich geschützt

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Green

Sammlungen

Chemie: Publikationen
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Journal of Organometallic Chemistry. 1989, 365(3), pp. 285-295. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(89)87027-5

Zusammenfassung

Infrared studies at a CO pressure of 120 bar show (η5-C5H5)2W(CO) to be completely resistant to an excess of CO in the absence of oxidants, but cyclovoltammetric measurements with this complex and with (η3-C5H5)(η5-C5H5)W(CO)2 in THF solution at 0°C indicate that the ring-slipped dicarbonyl complex is catalytically generated by a one-electron oxidation of the tungstenocene monocarbonyl under CO at ambient pressure. Similar results are found for the reaction of (η5-C5H5)2Mo(CO) with CO.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690MÖNKEBERG, Sigrid, Edith VAN RAAIJ, Herbert KIESELE, Hans-Herbert BRINTZINGER, 1989. CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes : Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis. In: Journal of Organometallic Chemistry. 1989, 365(3), pp. 285-295. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(89)87027-5
BibTex
@article{Monkeberg1989COind-23960,
  year={1989},
  doi={10.1016/0022-328X(89)87027-5},
  title={CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes : Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis},
  number={3},
  volume={365},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={285--295},
  author={Mönkeberg, Sigrid and van Raaij, Edith and Kiesele, Herbert and Brintzinger, Hans-Herbert}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/23960">
    <dc:contributor>van Raaij, Edith</dc:contributor>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:title>CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes : Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis</dcterms:title>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-09-05T12:37:02Z</dc:date>
    <dc:contributor>Mönkeberg, Sigrid</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/23960/1/Moenkeberg_239601.pdf"/>
    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
    <dcterms:issued>1989</dcterms:issued>
    <dc:creator>Kiesele, Herbert</dc:creator>
    <dc:contributor>Kiesele, Herbert</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-09-05T12:37:02Z</dcterms:available>
    <dc:creator>Brintzinger, Hans-Herbert</dc:creator>
    <dc:language>eng</dc:language>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dcterms:abstract xml:lang="eng">Infrared studies at a CO pressure of 120 bar show (η&lt;sup&gt;5&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;W(CO) to be completely resistant to an excess of CO in the absence of oxidants, but cyclovoltammetric measurements with this complex and with (η&lt;sup&gt;3&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)(η&lt;sup&gt;5&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)W(CO)&lt;sub&gt;2&lt;/sub&gt; in THF solution at 0°C indicate that the ring-slipped dicarbonyl complex is catalytically generated by a one-electron oxidation of the tungstenocene monocarbonyl under CO at ambient pressure. Similar results are found for the reaction of (η&lt;sup&gt;5&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;Mo(CO) with CO.</dcterms:abstract>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23960"/>
    <dc:creator>van Raaij, Edith</dc:creator>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/23960/1/Moenkeberg_239601.pdf"/>
    <dc:creator>Mönkeberg, Sigrid</dc:creator>
    <dc:rights>terms-of-use</dc:rights>
    <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 365 (1989), 3. - S. 285-295</dcterms:bibliographicCitation>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Begutachtet
Diese Publikation teilen