Publikation:

Ansa-metallocene derivatives : III. Influence of an interannular ethylene bridge on the reactivity of titanocene derivatives

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1981

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Smith, James A.

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http://nbn-resolving.de/urn:nbn:de:bsz:352-239559
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https://doi.org/10.1016/S0022-328X(00)86097-0
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Journal of Organometallic Chemistry. 1981, 218(2), pp. 159-167. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)86097-0

Zusammenfassung

Titanocene derivatives with an interannular ethylene bridge, while resembling their unbridged counterparts in many transformations involving TiIV or TillI oxidation stages, do not follow reaction paths previously observed for unbridged titanocene in a number of reactions, such as formation of a TiII dinitrogen complex, isotope exchange of the cyclopentadienyl riIig ligands with D2, or formation of a TiIII hydride compound. These reactions are considered to be blocked by the unavailability of a «free" titanocene species, [(CH2) sub>2-(C5H4)2TiII]n, as an intermediate in such systems.

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ISO 690SMITH, James A., Hans-Herbert BRINTZINGER, 1981. Ansa-metallocene derivatives : III. Influence of an interannular ethylene bridge on the reactivity of titanocene derivatives. In: Journal of Organometallic Chemistry. 1981, 218(2), pp. 159-167. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)86097-0
BibTex
@article{Smith1981Ansam-23955,
  year={1981},
  doi={10.1016/S0022-328X(00)86097-0},
  title={Ansa-metallocene derivatives : III. Influence of an interannular ethylene bridge on the reactivity of titanocene derivatives},
  number={2},
  volume={218},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={159--167},
  author={Smith, James A. and Brintzinger, Hans-Herbert}
}
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