Publikation: Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds
Lade...
Dateien
Datum
2018
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Hybrid
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Angewandte Chemie International Edition. Wiley-Blackwell - STM. 2018, 57(38), pp. 12270-12274. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.201801277
Zusammenfassung
Highly fused, fully conjugated aromatic compounds are interesting candidates for organic electronics. With higher crystallinity their electronic properties improve. It is shown here that the crystallization of three archetypes of such molecules-pentacenetetrone, indigo, and perinone-can be achieved hydrothermally. Given their molecular structure, this is a truly startling finding. In addition, it is demonstrated that perinone can also be synthesized in solely high-temperature water from the starting compounds naphthalene bisanhydride and o-phenylene diamine without the need for co-solvents or catalysts. The transformation can be drastically accelerated by the application of microwave irradiation. This is the first report on the hydrothermal generation of two fused heterocycles.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
carbonyl dyes, crystalline materials, fused heterocycles, green chemistry, hydrothermal synthesis
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
TAUBLAENDER, M. Josef, Florian GLÖCKLHOFER, Martina MARCHETTI-DESCHMANN, Miriam M. UNTERLASS, 2018. Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds. In: Angewandte Chemie International Edition. Wiley-Blackwell - STM. 2018, 57(38), pp. 12270-12274. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.201801277BibTex
@article{Taublaender2018-09-17Green-55236,
year={2018},
doi={10.1002/anie.201801277},
title={Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds},
number={38},
volume={57},
issn={0570-0833},
journal={Angewandte Chemie International Edition},
pages={12270--12274},
author={Taublaender, M. Josef and Glöcklhofer, Florian and Marchetti-Deschmann, Martina and Unterlass, Miriam M.}
}RDF
<rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/55236">
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/55236/3/Taublaender_2-gsm5fevps67i5.pdf"/>
<dc:contributor>Unterlass, Miriam M.</dc:contributor>
<dc:creator>Taublaender, M. Josef</dc:creator>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dcterms:rights rdf:resource="http://creativecommons.org/licenses/by/4.0/"/>
<dc:creator>Unterlass, Miriam M.</dc:creator>
<dc:creator>Glöcklhofer, Florian</dc:creator>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/55236/3/Taublaender_2-gsm5fevps67i5.pdf"/>
<dc:contributor>Glöcklhofer, Florian</dc:contributor>
<dcterms:issued>2018-09-17</dcterms:issued>
<dc:rights>Attribution 4.0 International</dc:rights>
<dc:language>eng</dc:language>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2021-10-13T09:37:27Z</dc:date>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dcterms:abstract xml:lang="eng">Highly fused, fully conjugated aromatic compounds are interesting candidates for organic electronics. With higher crystallinity their electronic properties improve. It is shown here that the crystallization of three archetypes of such molecules-pentacenetetrone, indigo, and perinone-can be achieved hydrothermally. Given their molecular structure, this is a truly startling finding. In addition, it is demonstrated that perinone can also be synthesized in solely high-temperature water from the starting compounds naphthalene bisanhydride and o-phenylene diamine without the need for co-solvents or catalysts. The transformation can be drastically accelerated by the application of microwave irradiation. This is the first report on the hydrothermal generation of two fused heterocycles.</dcterms:abstract>
<dc:contributor>Taublaender, M. Josef</dc:contributor>
<bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/55236"/>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2021-10-13T09:37:27Z</dcterms:available>
<dc:creator>Marchetti-Deschmann, Martina</dc:creator>
<dcterms:title>Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds</dcterms:title>
<dc:contributor>Marchetti-Deschmann, Martina</dc:contributor>
</rdf:Description>
</rdf:RDF>Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Nein
Begutachtet
Ja
