Publikation:

The Complexed Triphosphaallyl Radical, Cation, and Anion Family

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2009

Autor:innen

Scheer, Manfred
Kuntz, Christian
Stubenhofer, Markus
Sierka, Marek

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http://nbn-resolving.de/urn:nbn:de:bsz:352-137949
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https://doi.org/10.1002/anie.200805892
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Angewandte Chemie International Edition. 2009, 48(14), pp. 2600-2604. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200805892

Zusammenfassung

Radically complex: The photolytic reaction of [CpP{W(CO)5}2] (Cp=C5Me5) with a diphosphene produces, via a radical intermediate, an air-stable complexed triphosphaallyl radical, in which the unpaired electron is evenly distributed over both terminal P atoms. Oxidation of the radical leads to a triphosphaallyl cation, which is only stable at low temperatures in solution, whereas the stable triphosphaallyl anion is formed by reduction (see picture, Mes*=2,4,6-tri-tert-butylphenyl).

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540 Chemie

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ISO 690SCHEER, Manfred, Christian KUNTZ, Markus STUBENHOFER, Michael LINSEIS, Rainer F. WINTER, Marek SIERKA, 2009. The Complexed Triphosphaallyl Radical, Cation, and Anion Family. In: Angewandte Chemie International Edition. 2009, 48(14), pp. 2600-2604. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200805892
BibTex
@article{Scheer2009Compl-13794,
  year={2009},
  doi={10.1002/anie.200805892},
  title={The Complexed Triphosphaallyl Radical, Cation, and Anion Family},
  number={14},
  volume={48},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={2600--2604},
  author={Scheer, Manfred and Kuntz, Christian and Stubenhofer, Markus and Linseis, Michael and Winter, Rainer F. and Sierka, Marek}
}
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