Publikation: Capturing an amorphous BaSO4 intermediate precursor to barite
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2020
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CrystEngComm. Royal Society of Chemistry (RSC). 2020, 22(8), pp. 1310-1313. eISSN 1466-8033. Available under: doi: 10.1039/c9ce01555h
Zusammenfassung
The work presented here investigates the early stages of barium sulfate crystallization from aqueous solutions. By monitoring free-barium activity during the crystallization, we identified a metastable BaSO4 phase that precedes barite formation. Ex situ investigations provide direct, unambiguous experimental evidence of an amorphous BaSO4 phase in an additive-free scenario.
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540 Chemie
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RUIZ AGUDO, Cristina, David MCDONOGH, Jonathan Thomas AVARO, David Joshua SCHUPP, Denis GEBAUER, 2020. Capturing an amorphous BaSO4 intermediate precursor to barite. In: CrystEngComm. Royal Society of Chemistry (RSC). 2020, 22(8), pp. 1310-1313. eISSN 1466-8033. Available under: doi: 10.1039/c9ce01555hBibTex
@article{RuizAgudo2020-02-24Captu-49335,
year={2020},
doi={10.1039/c9ce01555h},
title={Capturing an amorphous BaSO<sub>4</sub> intermediate precursor to barite},
number={8},
volume={22},
journal={CrystEngComm},
pages={1310--1313},
author={Ruiz Agudo, Cristina and McDonogh, David and Avaro, Jonathan Thomas and Schupp, David Joshua and Gebauer, Denis}
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<dcterms:abstract xml:lang="eng">The work presented here investigates the early stages of barium sulfate crystallization from aqueous solutions. By monitoring free-barium activity during the crystallization, we identified a metastable BaSO<sub>4</sub> phase that precedes barite formation. Ex situ investigations provide direct, unambiguous experimental evidence of an amorphous BaSO<sub>4</sub> phase in an additive-free scenario.</dcterms:abstract>
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