[{Me4C2(C5H4)2}Zr(BH4)2], a bis(tetrahydroborate) complex of a bridged zirconocene

Schaper, Frank; Brintzinger, Hans-Herbert

[{Me₄C₂(C₅H₄)₂}Zr(BH₄)₂], a bis(tetrahydroborate) complex of a bridged zirconocene

Dateien

Schaper_238617.pdfGröße: 108.02 KBDownloads: 679

Datum

2000

Autor:innen

Schaper, Frank

Brintzinger, Hans-Herbert

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Acta Crystallographica Section C Crystal Structure Communications. 2000, 56(3), pp. e78-e78. ISSN 0108-2701. eISSN 1600-5759. Available under: doi: 10.1107/S0108270100002250

Zusammenfassung

The title compound, bis(tetrahydroborato)[1,1,2,2-tetramethyl-1,2-ethylenebis(Eta⁵-cyclopentadienyl)]zirconium, was obtained from the reaction of the zirconocene dichloride with lithium tetrahydroborate. The molecule adopts an approximate C_2v symmetry. Both tetrahydroborate ligands are Eta²-coordinated and tilted by 18-19° out of the equatorial plane.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

SCHAPER, Frank, Hans-Herbert BRINTZINGER, 2000. [{Me₄C₂(C₅H₄)₂}Zr(BH₄)₂], a bis(tetrahydroborate) complex of a bridged zirconocene. In: Acta Crystallographica Section C Crystal Structure Communications. 2000, 56(3), pp. e78-e78. ISSN 0108-2701. eISSN 1600-5759. Available under: doi: 10.1107/S0108270100002250

BibTex

@article{Schaper2000-03-15biste-23861,
  year={2000},
  doi={10.1107/S0108270100002250},
  title={[{Me<sub>4</sub>C<sub>2</sub>(C<sub>5</sub>H<sub>4</sub>)<sub>2</sub>}Zr(BH<sub>4</sub>)<sub>2</sub>], a bis(tetrahydroborate) complex of a bridged zirconocene},
  number={3},
  volume={56},
  issn={0108-2701},
  journal={Acta Crystallographica Section C Crystal Structure Communications},
  pages={e78--e78},
  author={Schaper, Frank and Brintzinger, Hans-Herbert}
}

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    <dcterms:title>[{Me&lt;sub&gt;4&lt;/sub&gt;C&lt;sub&gt;2&lt;/sub&gt;(C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;}Zr(BH&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;], a bis(tetrahydroborate) complex of a bridged zirconocene</dcterms:title>
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    <dcterms:abstract xml:lang="eng">The title compound, bis(tetrahydroborato)[1,1,2,2-tetramethyl-1,2-ethylenebis(Eta&lt;sup&gt;5&lt;/sup&gt;-cyclopentadienyl)]zirconium, was obtained from the reaction of the zirconocene dichloride with lithium tetrahydroborate. The molecule adopts an approximate C&lt;sub&gt;2v&lt;/sub&gt; symmetry. Both tetrahydroborate ligands are Eta&lt;sup&gt;2&lt;/sup&gt;-coordinated and tilted by 18-19° out of the equatorial plane.</dcterms:abstract>
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