Phosphoniothiolat–Komplexe : Darstellung und Umlagerung in Phosphan–Komplexe
| dc.contributor.author | Fischer, Helmut | |
| dc.contributor.author | Fluck, Klaus H. | deu |
| dc.contributor.author | Troll, Carsten | deu |
| dc.date.accessioned | 2013-06-28T11:11:40Z | deu |
| dc.date.available | 2013-06-28T11:11:40Z | deu |
| dc.date.issued | 1992 | |
| dc.description.abstract | Pentacarbonyl(thiobenzaldehyde)tungsten (1) reacts with phosphanes PR3 to give the phosphoniothiolate / complexes (CO)5W[SC(H)Ph(PR3)] (2) (R[DOUBLE BOND]Me, Et, Ph, 4–MeC6H4). Similarly, the thiobenzophenone complex (CO)5W[S[DOUBLE BOND]CPh2] (3) affords (CO)5W[SC(Ph)2PMe3] (4). The phosphoniothiolate complexes obtained from 1 and PPh2H or P(2,4,6–Me3C6H2)H2 rapidly rearrange by formal S,P migration of (CO)5W and P,C migration of H to form the phosphate complexes (CO)5W{P-(Ph)2[C(Ph)H(SH)]} (5) and (CO)5W{P(2,4,6–Me3C6H2)H-[C(Ph)H(SH)]} (6/6′). | eng |
| dc.description.version | published | |
| dc.identifier.citation | Chemische Berichte ; 125 (1992), 12. - S. 2675-2680 | deu |
| dc.identifier.doi | 10.1002/cber.19921251209 | deu |
| dc.identifier.uri | http://kops.uni-konstanz.de/handle/123456789/23451 | |
| dc.language.iso | eng | deu |
| dc.legacy.dateIssued | 2013-06-28 | deu |
| dc.rights | terms-of-use | deu |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | deu |
| dc.subject.ddc | 540 | deu |
| dc.title | Phosphoniothiolat–Komplexe : Darstellung und Umlagerung in Phosphan–Komplexe | eng |
| dc.type | JOURNAL_ARTICLE | deu |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Fischer1992Phosp-23451,
year={1992},
doi={10.1002/cber.19921251209},
title={Phosphoniothiolat–Komplexe : Darstellung und Umlagerung in Phosphan–Komplexe},
number={12},
volume={125},
issn={0009-2940},
journal={Chemische Berichte},
pages={2675--2680},
author={Fischer, Helmut and Fluck, Klaus H. and Troll, Carsten}
} | |
| kops.citation.iso690 | FISCHER, Helmut, Klaus H. FLUCK, Carsten TROLL, 1992. Phosphoniothiolat–Komplexe : Darstellung und Umlagerung in Phosphan–Komplexe. In: Chemische Berichte. 1992, 125(12), pp. 2675-2680. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/cber.19921251209 | deu |
| kops.citation.iso690 | FISCHER, Helmut, Klaus H. FLUCK, Carsten TROLL, 1992. Phosphoniothiolat–Komplexe : Darstellung und Umlagerung in Phosphan–Komplexe. In: Chemische Berichte. 1992, 125(12), pp. 2675-2680. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/cber.19921251209 | eng |
| kops.citation.rdf | <rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/23451">
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
<dc:creator>Troll, Carsten</dc:creator>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23451"/>
<dc:creator>Fischer, Helmut</dc:creator>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-06-28T11:11:40Z</dc:date>
<dc:creator>Fluck, Klaus H.</dc:creator>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dcterms:abstract xml:lang="eng">Pentacarbonyl(thiobenzaldehyde)tungsten (1) reacts with phosphanes PR3 to give the phosphoniothiolate / complexes (CO)5W[SC(H)Ph(PR3)] (2) (R[DOUBLE BOND]Me, Et, Ph, 4–MeC6H4). Similarly, the thiobenzophenone complex (CO)5W[S[DOUBLE BOND]CPh2] (3) affords (CO)5W[SC(Ph)2PMe3] (4). The phosphoniothiolate complexes obtained from 1 and PPh2H or P(2,4,6–Me3C6H2)H2 rapidly rearrange by formal S,P migration of (CO)5W and P,C migration of H to form the phosphate complexes (CO)5W{P-(Ph)2[C(Ph)H(SH)]} (5) and (CO)5W{P(2,4,6–Me3C6H2)H-[C(Ph)H(SH)]} (6/6′).</dcterms:abstract>
<dc:contributor>Fluck, Klaus H.</dc:contributor>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-06-28T11:11:40Z</dcterms:available>
<dcterms:issued>1992</dcterms:issued>
<dc:language>eng</dc:language>
<dc:contributor>Troll, Carsten</dc:contributor>
<dc:contributor>Fischer, Helmut</dc:contributor>
<dcterms:bibliographicCitation>Chemische Berichte ; 125 (1992), 12. - S. 2675-2680</dcterms:bibliographicCitation>
<dcterms:title>Phosphoniothiolat–Komplexe : Darstellung und Umlagerung in Phosphan–Komplexe</dcterms:title>
<dc:rights>terms-of-use</dc:rights>
</rdf:Description>
</rdf:RDF> | |
| kops.flag.knbibliography | false | |
| kops.identifier.nbn | urn:nbn:de:bsz:352-234511 | deu |
| kops.sourcefield | Chemische Berichte. 1992, <b>125</b>(12), pp. 2675-2680. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/cber.19921251209 | deu |
| kops.sourcefield.plain | Chemische Berichte. 1992, 125(12), pp. 2675-2680. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/cber.19921251209 | deu |
| kops.sourcefield.plain | Chemische Berichte. 1992, 125(12), pp. 2675-2680. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/cber.19921251209 | eng |
| kops.submitter.email | karin.hoch@uni-konstanz.de | deu |
| relation.isAuthorOfPublication | 726c19aa-617a-4eb9-9a10-3747eff2ffc8 | |
| relation.isAuthorOfPublication.latestForDiscovery | 726c19aa-617a-4eb9-9a10-3747eff2ffc8 | |
| source.bibliographicInfo.fromPage | 2675 | |
| source.bibliographicInfo.issue | 12 | |
| source.bibliographicInfo.toPage | 2680 | |
| source.bibliographicInfo.volume | 125 | |
| source.identifier.eissn | 1099-0682 | deu |
| source.identifier.issn | 0009-2940 | |
| source.periodicalTitle | Chemische Berichte |
Dateien
Lizenzbündel
1 - 1 von 1
Vorschaubild nicht verfügbar
- Name:
- license.txt
- Größe:
- 1.92 KB
- Format:
- Plain Text
- Beschreibung:
