@article{Machatschek2016-06-02Assem-35496,
  year={2016},
  doi={10.3762/bjnano.7.70},
  title={Assembling semiconducting molecules by covalent attachment to a lamellar crystalline polymer substrate},
  volume={7},
  journal={Beilstein Journal of Nanotechnology},
  pages={784--798},
  author={Machatschek, Rainhard and Ortmann, Patrick and Reiter, Renate and Mecking, Stefan and Reiter, Günter}
}

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    <dc:contributor>Reiter, Günter</dc:contributor>
    <dc:rights>Attribution 2.0 Generic</dc:rights>
    <dc:contributor>Mecking, Stefan</dc:contributor>
    <dc:creator>Reiter, Renate</dc:creator>
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    <dcterms:abstract xml:lang="eng">We have investigated the potential of polymers containing precisely spaced side-branches for thin film applications, particularly in the context of organic electronics. Upon crystallization, the side-branches were excluded from the crystalline core of a lamellar crystal. Thus, the surfaces of these crystals were covered by side-branches. By using carboxyl groups as side-branches, which allow for chemical reactions, we could functionalize the crystal with semiconducting molecules. Here, we compare properties of crystals differing in size: small nanocrystals and large single crystals. By assembling nanocrystals on a Langmuir trough, large areas could be covered by monolayers consisting of randomly arranged nanocrystals. Alternatively, we used a method based on local supersaturation to grow large area single crystals of the precisely side-branched polymer from solution. Attachment of the semiconducting molecules to the lamellar surface of large single crystals was possible, however, only after an appropriate annealing procedure. As a function of the duration of the grafting process, the morphology of the resulting layer of semiconducting molecules changed from patchy to compact.</dcterms:abstract>
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    <dc:creator>Machatschek, Rainhard</dc:creator>
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    <dcterms:title>Assembling semiconducting molecules by covalent attachment to a lamellar crystalline polymer substrate</dcterms:title>
    <dc:contributor>Ortmann, Patrick</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-10-07T13:01:32Z</dc:date>
    <dc:contributor>Reiter, Renate</dc:contributor>
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    <dc:contributor>Machatschek, Rainhard</dc:contributor>
    <dc:creator>Ortmann, Patrick</dc:creator>
    <dcterms:issued>2016-06-02</dcterms:issued>
    <dc:creator>Reiter, Günter</dc:creator>
    <dc:creator>Mecking, Stefan</dc:creator>
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