@article{NeiraCarrillo2016-08-23Templ-35310,
  year={2016},
  doi={10.1021/acs.langmuir.6b02536},
  title={Templated CaCO<sub>3</sub> Crystallization by Submicrometer and Nanosized Fibers},
  number={35},
  volume={32},
  issn={0743-7463},
  journal={Langmuir},
  pages={8951--8959},
  author={Neira-Carrillo, Andrónico and Gentsch, Rafael and Börner, Hans G. and Acevedo, Diego Fernando and Barbero, Cesar Alfredo and Cölfen, Helmut}
}

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    <dc:contributor>Gentsch, Rafael</dc:contributor>
    <dc:contributor>Börner, Hans G.</dc:contributor>
    <dc:creator>Cölfen, Helmut</dc:creator>
    <dc:creator>Acevedo, Diego Fernando</dc:creator>
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    <dc:contributor>Cölfen, Helmut</dc:contributor>
    <dc:contributor>Barbero, Cesar Alfredo</dc:contributor>
    <dc:creator>Barbero, Cesar Alfredo</dc:creator>
    <dc:language>eng</dc:language>
    <dcterms:abstract xml:lang="eng">Electrospun submicrometer-sized poly(ε-caprolactone) (PCL) meshes and nanosized multiwalled carbon nanotubes (MWCNTs) were used as a template for preparing porous and interconnected inorganic-organic hybrid materials composed of CaCO&lt;sub&gt;3&lt;/sub&gt;. Herein, we describe the proportion and incorporation method of submicrometer-sized plasma-treated PCL meshes over areas &gt;1 mm&lt;sup&gt;2&lt;/sup&gt; with CaCO&lt;sub&gt;3&lt;/sub&gt; using three crystallization methods including the use of poly(acrylic acid) (PAA). We found that flexible and rigid acid-functionalized MWCNTs showed a clear capacity and effects to penetrate calcite particles. MWCNTs interacted differently with the individual growth planes of CaCO&lt;sub&gt;3&lt;/sub&gt;, indicating that fibers can undergo changes depending on sulfonate or carboxylate groups, adopt different orientations in solution, and thereby elicit changes in CaCO&lt;sub&gt;3&lt;/sub&gt; morphology. In summary, the use of PCL and acidic MWCNT fibers as an additive for substrate templates and experimental crystallization provides a viable approach for studying various aspects of biomineralization, including the production of controlled particles, control of porosities, and defined morphologies at microscale and nanoscale levels.</dcterms:abstract>
    <dc:creator>Börner, Hans G.</dc:creator>
    <dcterms:title>Templated CaCO&lt;sub&gt;3&lt;/sub&gt; Crystallization by Submicrometer and Nanosized Fibers</dcterms:title>
    <dc:contributor>Neira-Carrillo, Andrónico</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-09-15T13:36:54Z</dc:date>
    <dc:contributor>Acevedo, Diego Fernando</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-09-15T13:36:54Z</dcterms:available>
    <dc:creator>Neira-Carrillo, Andrónico</dc:creator>
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    <dc:creator>Gentsch, Rafael</dc:creator>
    <dcterms:issued>2016-08-23</dcterms:issued>
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