@article{Mathies2016-01-07Pulse-43420,
  year={2016},
  doi={10.1021/acs.jpclett.5b02720},
  title={Pulsed Dynamic Nuclear Polarization with Trityl Radicals},
  number={1},
  volume={7},
  journal={The Journal of Physical Chemistry Letters},
  pages={111--116},
  author={Mathies, Guinevere and Jain, Sheetal and Reese, Marcel and Griffin, Robert G.}
}

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/43420">
    <dc:creator>Mathies, Guinevere</dc:creator>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:contributor>Reese, Marcel</dc:contributor>
    <dcterms:issued>2016-01-07</dcterms:issued>
    <dc:language>eng</dc:language>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2018-10-02T12:46:16Z</dcterms:available>
    <dcterms:abstract xml:lang="eng">Continuous-wave (CW) dynamic nuclear polarization (DNP) is now established as a method of choice to enhance the sensitivity in a variety of NMR experiments. Nevertheless, there remains a need for the development of more efficient methods to transfer polarization from electrons to nuclei. Of particular interest are pulsed DNP methods because they enable a rapid and efficient polarization transfer that, in contrast with CW DNP methods, is not attenuated at high magnetic fields. Here we report nuclear spin orientation via electron spin-locking (NOVEL) experiments using the polarizing agent trityl OX063 in glycerol/water at a temperature of 80 K and a magnetic field of 0.34 T. &lt;sup&gt;1&lt;/sup&gt;H NMR signal enhancements up to 430 are observed, and the buildup of the local polarization occurs in a few hundred nanoseconds. Thus, NOVEL can efficiently dynamically polarize &lt;sup&gt;1&lt;/sup&gt;H atoms in a system that is of general interest to the solid-state DNP NMR community. This is a first, important step toward the general application of pulsed DNP at higher fields.</dcterms:abstract>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:title>Pulsed Dynamic Nuclear Polarization with Trityl Radicals</dcterms:title>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:creator>Jain, Sheetal</dc:creator>
    <dc:creator>Griffin, Robert G.</dc:creator>
    <dc:creator>Reese, Marcel</dc:creator>
    <dc:contributor>Jain, Sheetal</dc:contributor>
    <dc:contributor>Griffin, Robert G.</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2018-10-02T12:46:16Z</dc:date>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/43420"/>
    <dc:contributor>Mathies, Guinevere</dc:contributor>
  </rdf:Description>
</rdf:RDF>