Electronic level structure of group III heavy element clusters studied by photoelectron spectroscopy

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IntJMassSpecIonProc1021990.pdf
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1990
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Gausa, Michael
Lutz, Hans O.
Meiwes-Broer, Karl-Heinz
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UV-photoelectrons of mass-defined indium and thallium cluster anions have been analyzed at a detachment energy of 3.68 eV in the size range n = 2 20. The photoelectron threshold energies are in rough agreement with the values predicted by the metal droplet model. A number of low-lying excited states of the neutral-clusters are detected. The high atomic s-orbital binding energies appear to induce alkali-like character of In−n and Tl−n.

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ISO 690GAUSA, Michael, Gerd GANTEFÖR, Hans O. LUTZ, Karl-Heinz MEIWES-BROER, 1990. Electronic level structure of group III heavy element clusters studied by photoelectron spectroscopy. In: International Journal of Mass Spectrometry and Ion Processes. 1990, 102, pp. 227-237. Available under: doi: 10.1016/0168-1176(90)80062-8
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@article{Gausa1990Elect-9457,
  year={1990},
  doi={10.1016/0168-1176(90)80062-8},
  title={Electronic level structure of group III heavy element clusters studied by photoelectron spectroscopy},
  volume={102},
  journal={International Journal of Mass Spectrometry and Ion Processes},
  pages={227--237},
  author={Gausa, Michael and Ganteför, Gerd and Lutz, Hans O. and Meiwes-Broer, Karl-Heinz}
}
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