Publikation:

Cobalt-mediated regioselective synthesis of substituted tetrahydroquinolines

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2005

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Kesenheimer, Christian
Kalogerakis, Aris

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Published

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Synlett. 2005(11), pp. 1758-1760. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2005-871568

Zusammenfassung

A regioselective synthesis of polycyclic substituted ­pyridines is reported. Key step is the cobalt-catalyzed intramole­cular cyclization of diynenitriles, tethered by a silicon oxygen bond. Subsequent opening of the Si-O ring led then to the related tetra­hydroquinolines.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

cobalt, catalysis, cycloaddition, pyridines, quinolines, ergot alkaloids

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ISO 690GROTH, Ulrich, Thomas HUHN, Christian KESENHEIMER, Aris KALOGERAKIS, 2005. Cobalt-mediated regioselective synthesis of substituted tetrahydroquinolines. In: Synlett. 2005(11), pp. 1758-1760. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2005-871568
BibTex
@article{Groth2005Cobal-9820,
  year={2005},
  doi={10.1055/s-2005-871568},
  title={Cobalt-mediated regioselective synthesis of substituted tetrahydroquinolines},
  number={11},
  issn={0936-5214},
  journal={Synlett},
  pages={1758--1760},
  author={Groth, Ulrich and Huhn, Thomas and Kesenheimer, Christian and Kalogerakis, Aris}
}
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