A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

Titz, Alexander; Radic, Zorana; Schwardt, Oliver; Ernst, Beat

A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

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Date

2006

Authors

Titz, Alexander

Radic, Zorana

Schwardt, Oliver

Ernst, Beat

Publication type

Journal article

Published in

Tetrahedron Letters ; 47 (2006), 14. - pp. 2383-2385. - ISSN 0040-4039

Abstract

A safe and convenient method for the copper(II)-catalyzed diazo transfer from triflyl azide to primary amines is reported.
By replacing CH2Cl2 by toluene the formation of hazardous side products, for example, azido-chloromethane and diazidomethane can be avoided.

Subject (DDC)

540 Chemistry

Cite This

ISO 690

TITZ, Alexander, Zorana RADIC, Oliver SCHWARDT, Beat ERNST, 2006. A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines. In: Tetrahedron Letters. 47(14), pp. 2383-2385. ISSN 0040-4039. Available under: doi: 10.1016/j.tetlet.2006.01.157

BibTex

@article{Titz2006conve-17132,
  year={2006},
  doi={10.1016/j.tetlet.2006.01.157},
  title={A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines},
  number={14},
  volume={47},
  issn={0040-4039},
  journal={Tetrahedron Letters},
  pages={2383--2385},
  author={Titz, Alexander and Radic, Zorana and Schwardt, Oliver and Ernst, Beat}
}

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