A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

Titz, Alexander; Radic, Zorana; Schwardt, Oliver; Ernst, Beat

A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

Dateien

Zu diesem Dokument gibt es keine Dateien.

Datum

2006

Autor:innen

Titz, Alexander

Radic, Zorana

Schwardt, Oliver

Ernst, Beat

Publikationstyp

Zeitschriftenartikel

unikn.publication.listelement.citation.prefix.version.undefined

Tetrahedron Letters. 2006, 47(14), pp. 2383-2385. ISSN 0040-4039. Available under: doi: 10.1016/j.tetlet.2006.01.157

Zusammenfassung

A safe and convenient method for the copper(II)-catalyzed diazo transfer from triflyl azide to primary amines is reported.
By replacing CH2Cl2 by toluene the formation of hazardous side products, for example, azido-chloromethane and diazidomethane can be avoided.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

TITZ, Alexander, Zorana RADIC, Oliver SCHWARDT, Beat ERNST, 2006. A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines. In: Tetrahedron Letters. 2006, 47(14), pp. 2383-2385. ISSN 0040-4039. Available under: doi: 10.1016/j.tetlet.2006.01.157

BibTex

@article{Titz2006conve-17132,
  year={2006},
  doi={10.1016/j.tetlet.2006.01.157},
  title={A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines},
  number={14},
  volume={47},
  issn={0040-4039},
  journal={Tetrahedron Letters},
  pages={2383--2385},
  author={Titz, Alexander and Radic, Zorana and Schwardt, Oliver and Ernst, Beat}
}

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    <dcterms:abstract xml:lang="eng">A safe and convenient method for the copper(II)-catalyzed diazo transfer from triflyl azide to primary amines is reported.&lt;br /&gt;By replacing CH2Cl2 by toluene the formation of hazardous side products, for example, azido-chloromethane and diazidomethane can be avoided.</dcterms:abstract>
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