Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E=B–In)

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2001
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Uhl, Werner
Cuypers, Lars
Harms, Klaus
Kaim, Wolfgang
Wanner, Matthias
Koch, Rainer
Saak, Wolfgang
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Angewandte Chemie International Edition. 2001, 40(3), pp. 566-568. ISSN 1433-7851. Available under: doi: 10.1002/1521-3773(20010202)40:3<566::AID-ANIE566>3.0.CO;2-T
Zusammenfassung

A simple preparative method has been employed for the synthesis of the novel cluster compound Ga9(CMe3)9, which contains a tricapped trigonal prism of monovalent gallium atoms. Electron transfer processes were observed similar to those of polyboranes, leading to the the reversible formation of the corresponding radical anion.

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ISO 690UHL, Werner, Lars CUYPERS, Klaus HARMS, Wolfgang KAIM, Matthias WANNER, Rainer F. WINTER, Rainer KOCH, Wolfgang SAAK, 2001. Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E=B–In). In: Angewandte Chemie International Edition. 2001, 40(3), pp. 566-568. ISSN 1433-7851. Available under: doi: 10.1002/1521-3773(20010202)40:3<566::AID-ANIE566>3.0.CO;2-T
BibTex
@article{Uhl2001Ga9CM-13817,
  year={2001},
  doi={10.1002/1521-3773(20010202)40:3<566::AID-ANIE566>3.0.CO;2-T},
  title={Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E=B–In)},
  number={3},
  volume={40},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={566--568},
  author={Uhl, Werner and Cuypers, Lars and Harms, Klaus and Kaim, Wolfgang and Wanner, Matthias and Winter, Rainer F. and Koch, Rainer and Saak, Wolfgang}
}
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