Viscoelasticity of Depletion-Induced Gels in Emulsion-Polymer Systems
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1999
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Langmuir. 1999, 15(6), pp. 1918-1922. Available under: doi: 10.1021/la9812424
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Using rheometry and light scattering, we have studied the viscoelasticity of gels formed by the kinetically arrested phase separation in an emulsion-polymer mixture; to prevent the gels from collapsing under their own weight, we have used an isopycnic solvent. At constant osmotic pressure (set by the polymer concentration) and droplet volume fractions ø well above the gelation transition, we find the elastic modulus to increase roughly linearly with ø, indicating an entropic elasticity based on the cluster packing.
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MELLER, Anton, Thomas GISLER, David A. WEITZ, Joel STAVANS, 1999. Viscoelasticity of Depletion-Induced Gels in Emulsion-Polymer Systems. In: Langmuir. 1999, 15(6), pp. 1918-1922. Available under: doi: 10.1021/la9812424BibTex
@article{Meller1999Visco-4734, year={1999}, doi={10.1021/la9812424}, title={Viscoelasticity of Depletion-Induced Gels in Emulsion-Polymer Systems}, number={6}, volume={15}, journal={Langmuir}, pages={1918--1922}, author={Meller, Anton and Gisler, Thomas and Weitz, David A. and Stavans, Joel} }
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