Theory for the reorientational dynamics in glass-forming liquids

Franosch, Thomas; Fuchs, Matthias; Götze, Wolfgang; Mayr, Matthias R.; Singh, A. P.

Theory for the reorientational dynamics in glass-forming liquids

Dateien

Theory_for_the_reorientational_dynamics_in_glass_forming_liquids.pdfGröße: 369.59 KBDownloads: 356

Datum

1997

Autor:innen

Franosch, Thomas

Fuchs, Matthias

Götze, Wolfgang

Mayr, Matthias R.

Singh, A. P.

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Physik

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Physical Review E. 1997, 56(5), pp. 5659-5674. Available under: doi: 10.1103/PhysRevE.56.5659

Zusammenfassung

The mode-coupling for ideal liquid-glass transitions is extended so that the structural relaxation for the reorientational degrees of freedom of a linear molecule, which is immersed in a system of spherical particles, can be described. Closed equations of motion for the correlation functions formed with tensor density fluctuations are derived, which deal with the molecule's translational and reorientational motion. From these equations the nonergodicity parameters of a hard dumbbell molecule are calculated, which quantify its arrest in a hard-sphere glass. For top-down symmetric molecules it is shown that the odd-angular-momentum variables can exhibit an ergodic-to-nonergodic transition, characterized by a continuous increase of the Edwards-Anderson parameters near the critical points.

Fachgebiet (DDC)

530 Physik

Zitieren

ISO 690

FRANOSCH, Thomas, Matthias FUCHS, Wolfgang GÖTZE, Matthias R. MAYR, A. P. SINGH, 1997. Theory for the reorientational dynamics in glass-forming liquids. In: Physical Review E. 1997, 56(5), pp. 5659-5674. Available under: doi: 10.1103/PhysRevE.56.5659

BibTex

@article{Franosch1997Theor-4814,
  year={1997},
  doi={10.1103/PhysRevE.56.5659},
  title={Theory for the reorientational dynamics in glass-forming liquids},
  number={5},
  volume={56},
  journal={Physical Review E},
  pages={5659--5674},
  author={Franosch, Thomas and Fuchs, Matthias and Götze, Wolfgang and Mayr, Matthias R. and Singh, A. P.}
}

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