Application of the Rodriguez–Pattenden Photo-Ring Contraction : Total Synthesis and Configurational Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol

Weinstabl, Harald; Gaich, Tanja; Mulzer, Johann

Application of the Rodriguez–Pattenden Photo-Ring Contraction : Total Synthesis and Configurational Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol

Dateien

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Datum

2012

Autor:innen

Weinstabl, Harald

Gaich, Tanja

Mulzer, Johann

DOI (zitierfähiger Link)

https://doi.org/10.1021/ol301068h

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Organic Letters. 2012, 14(11), pp. 2834-2837. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/ol301068h

Zusammenfassung

A stereospecific photochemical ring contraction was used as the key step in the first total synthesis of the marine pseudopteranyl diterpene 11-gorgiacerol and its 11-epimer. The synthesis allowed the correction of the configurations that had been misassigned in the literature. In addition, some novel pseudopteranyl derivatives have been made.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

WEINSTABL, Harald, Tanja GAICH, Johann MULZER, 2012. Application of the Rodriguez–Pattenden Photo-Ring Contraction : Total Synthesis and Configurational Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol. In: Organic Letters. 2012, 14(11), pp. 2834-2837. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/ol301068h

BibTex

@article{Weinstabl2012-06Appli-38264,
  year={2012},
  doi={10.1021/ol301068h},
  title={Application of the Rodriguez–Pattenden Photo-Ring Contraction : Total Synthesis and Configurational Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol},
  number={11},
  volume={14},
  issn={1523-7060},
  journal={Organic Letters},
  pages={2834--2837},
  author={Weinstabl, Harald and Gaich, Tanja and Mulzer, Johann}
}

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