Application of the Rodriguez–Pattenden Photo-Ring Contraction : Total Synthesis and Configurational Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol

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2012
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Weinstabl, Harald
Mulzer, Johann
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Organic Letters ; 14 (2012), 11. - S. 2834-2837. - ISSN 1523-7060. - eISSN 1523-7052
Zusammenfassung
A stereospecific photochemical ring contraction was used as the key step in the first total synthesis of the marine pseudopteranyl diterpene 11-gorgiacerol and its 11-epimer. The synthesis allowed the correction of the configurations that had been misassigned in the literature. In addition, some novel pseudopteranyl derivatives have been made.
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ISO 690WEINSTABL, Harald, Tanja GAICH, Johann MULZER, 2012. Application of the Rodriguez–Pattenden Photo-Ring Contraction : Total Synthesis and Configurational Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol. In: Organic Letters. 14(11), pp. 2834-2837. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/ol301068h
BibTex
@article{Weinstabl2012-06Appli-38264,
  year={2012},
  doi={10.1021/ol301068h},
  title={Application of the Rodriguez–Pattenden Photo-Ring Contraction : Total Synthesis and Configurational Reassignment of 11-Gorgiacerol and 11-Epigorgiacerol},
  number={11},
  volume={14},
  issn={1523-7060},
  journal={Organic Letters},
  pages={2834--2837},
  author={Weinstabl, Harald and Gaich, Tanja and Mulzer, Johann}
}
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