Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates
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Other than their established short-chain congeners, polycondensates based on long-chain difunctional monomers are often dominated by the long methylene sequences of the repeat units in their solid-state structures and properties. This places them between traditional polycondensates and polyethylenes. The availability of long-chain monomers as a key prerequisite has benefited much from advances in the catalytic conversion of plant oils, via biotechnological and purely chemical approaches, likewise. This has promoted studies of, among others, applications-relevant properties. A comprehensive account is given of long-chain monomer syntheses and the preparation and physical properties, morphologies, mechanical behavior, and degradability of long-chain polyester, polyamides, polyurethanes, polyureas, polyacetals, and polycarbonates.
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STEMPFLE, Florian, Patrick ORTMANN, Stefan MECKING, 2016. Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates. In: Chemical Reviews. 2016, 116(7), pp. 4597-4641. ISSN 0009-2665. eISSN 1520-6890. Available under: doi: 10.1021/acs.chemrev.5b00705BibTex
@article{Stempfle2016-04-13LongC-33628, year={2016}, doi={10.1021/acs.chemrev.5b00705}, title={Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates}, number={7}, volume={116}, issn={0009-2665}, journal={Chemical Reviews}, pages={4597--4641}, author={Stempfle, Florian and Ortmann, Patrick and Mecking, Stefan} }
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