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Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates

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2016

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https://doi.org/10.1021/acs.chemrev.5b00705
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Chemical Reviews. 2016, 116(7), pp. 4597-4641. ISSN 0009-2665. eISSN 1520-6890. Available under: doi: 10.1021/acs.chemrev.5b00705

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Other than their established short-chain congeners, polycondensates based on long-chain difunctional monomers are often dominated by the long methylene sequences of the repeat units in their solid-state structures and properties. This places them between traditional polycondensates and polyethylenes. The availability of long-chain monomers as a key prerequisite has benefited much from advances in the catalytic conversion of plant oils, via biotechnological and purely chemical approaches, likewise. This has promoted studies of, among others, applications-relevant properties. A comprehensive account is given of long-chain monomer syntheses and the preparation and physical properties, morphologies, mechanical behavior, and degradability of long-chain polyester, polyamides, polyurethanes, polyureas, polyacetals, and polycarbonates.

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ISO 690STEMPFLE, Florian, Patrick ORTMANN, Stefan MECKING, 2016. Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates. In: Chemical Reviews. 2016, 116(7), pp. 4597-4641. ISSN 0009-2665. eISSN 1520-6890. Available under: doi: 10.1021/acs.chemrev.5b00705
BibTex
@article{Stempfle2016-04-13LongC-33628,
  year={2016},
  doi={10.1021/acs.chemrev.5b00705},
  title={Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates},
  number={7},
  volume={116},
  issn={0009-2665},
  journal={Chemical Reviews},
  pages={4597--4641},
  author={Stempfle, Florian and Ortmann, Patrick and Mecking, Stefan}
}
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