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Gel-Like Calcium Carbonate Precursors Observed by in situ AFM

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2017

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Caballero, Leonardo
Melo, Francisco

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https://doi.org/10.1021/acs.langmuir.6b03974
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Langmuir. 2017, 33(1), pp. 158-163. ISSN 0743-7463. eISSN 1520-5827. Available under: doi: 10.1021/acs.langmuir.6b03974

Zusammenfassung

The debate about crystallization processes is still ongoing and nonclassical crystallization mechanisms attract more and more attention. This work indicates that polymer induced liquid precursor (PILP) phases play a role for nonclassical calcium carbonate crystallization and growth processes. Here we report the observation of gel-like precursors for the crystal growth on a calcite surface by means of an in situ AFM study. These precursors spread out on the surface with time supporting their liquid character. This study will give new insights into biomineralization and crystallization processes in general.

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540 Chemie

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ISO 690WOLF, Stefan L. P., Leonardo CABALLERO, Francisco MELO, Helmut CÖLFEN, 2017. Gel-Like Calcium Carbonate Precursors Observed by in situ AFM. In: Langmuir. 2017, 33(1), pp. 158-163. ISSN 0743-7463. eISSN 1520-5827. Available under: doi: 10.1021/acs.langmuir.6b03974
BibTex
@article{Wolf2017-01-10GelLi-37424,
  year={2017},
  doi={10.1021/acs.langmuir.6b03974},
  title={Gel-Like Calcium Carbonate Precursors Observed by in situ AFM},
  number={1},
  volume={33},
  issn={0743-7463},
  journal={Langmuir},
  pages={158--163},
  author={Wolf, Stefan L. P. and Caballero, Leonardo and Melo, Francisco and Cölfen, Helmut}
}
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