Publikation: From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization
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Chemical Communications. Royal Society of Chemistry (RSC). 2014, 50(4), pp. 430-432. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C3CC47674J
Zusammenfassung
Fully aromatic polyimides are synthesized via solid-state polymerization of the corresponding monomer salts. The crystal structure of salts shows strong hydrogen bonding of the reactive groups and thereby paves the way for solid-state transformations. The polycondensation yields copies of the initial salt crystallite habits, accompanied by the development of a porosity especially suited for CO2.
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UNTERLASS, Miriam M., Franziska EMMERLING, Markus ANTONIETTI, Jens WEBER, 2014. From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization. In: Chemical Communications. Royal Society of Chemistry (RSC). 2014, 50(4), pp. 430-432. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C3CC47674JBibTex
@article{Unterlass2014dense-54824,
year={2014},
doi={10.1039/C3CC47674J},
title={From dense monomer salt crystals to CO<sub>2</sub> selective microporous polyimides via solid-state polymerization},
number={4},
volume={50},
issn={1359-7345},
journal={Chemical Communications},
pages={430--432},
author={Unterlass, Miriam M. and Emmerling, Franziska and Antonietti, Markus and Weber, Jens}
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<dcterms:abstract xml:lang="eng">Fully aromatic polyimides are synthesized via solid-state polymerization of the corresponding monomer salts. The crystal structure of salts shows strong hydrogen bonding of the reactive groups and thereby paves the way for solid-state transformations. The polycondensation yields copies of the initial salt crystallite habits, accompanied by the development of a porosity especially suited for CO<sub>2</sub>.</dcterms:abstract>
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