From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization

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2014
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Emmerling, Franziska
Antonietti, Markus
Weber, Jens
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Fully aromatic polyimides are synthesized via solid-state polymerization of the corresponding monomer salts. The crystal structure of salts shows strong hydrogen bonding of the reactive groups and thereby paves the way for solid-state transformations. The polycondensation yields copies of the initial salt crystallite habits, accompanied by the development of a porosity especially suited for CO2.

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ISO 690UNTERLASS, Miriam M., Franziska EMMERLING, Markus ANTONIETTI, Jens WEBER, 2014. From dense monomer salt crystals to CO2 selective microporous polyimides via solid-state polymerization. In: Chemical Communications. Royal Society of Chemistry (RSC). 2014, 50(4), pp. 430-432. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C3CC47674J
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@article{Unterlass2014dense-54824,
  year={2014},
  doi={10.1039/C3CC47674J},
  title={From dense monomer salt crystals to CO<sub>2</sub> selective microporous polyimides via solid-state polymerization},
  number={4},
  volume={50},
  issn={1359-7345},
  journal={Chemical Communications},
  pages={430--432},
  author={Unterlass, Miriam M. and Emmerling, Franziska and Antonietti, Markus and Weber, Jens}
}
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