Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

Burkart, Stefan; Blessing, Nico; Klipp, Björn; Müller, Jürgen; Ganteför, Gerd; Seifert, Gotthard

Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

Dateien

ChemPhysLett30119995_6.pdfGröße: 296.77 KBDownloads: 404

Datum

1999

Autor:innen

Burkart, Stefan

Blessing, Nico

Klipp, Björn

Müller, Jürgen

Ganteför, Gerd

Seifert, Gotthard

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Physik

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Chemical Physics Letters. 1999, 301(5-6), pp. 546-550. Available under: doi: 10.1016/S0009-2614(98)01428-6

Zusammenfassung

Photoelectron spectra of mass-separated, negatively charged, bare and reacted aluminium clusters AlnHm− (n=12 14, m=0 2) are presented and compared to the results of corresponding calculations. A large HOMO LUMO gap of 1.4 eV is found for the neutral Al13H cluster, indicating an extraordinarily high stability of this cluster. Adsorption of a second hydrogen atom results in the disappearance of the gap.

Fachgebiet (DDC)

530 Physik

Zitieren

ISO 690

BURKART, Stefan, Nico BLESSING, Björn KLIPP, Jürgen MÜLLER, Gerd GANTEFÖR, Gotthard SEIFERT, 1999. Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?. In: Chemical Physics Letters. 1999, 301(5-6), pp. 546-550. Available under: doi: 10.1016/S0009-2614(98)01428-6

BibTex

@article{Burkart1999Exper-4681,
  year={1999},
  doi={10.1016/S0009-2614(98)01428-6},
  title={Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?},
  number={5-6},
  volume={301},
  journal={Chemical Physics Letters},
  pages={546--550},
  author={Burkart, Stefan and Blessing, Nico and Klipp, Björn and Müller, Jürgen and Ganteför, Gerd and Seifert, Gotthard}
}

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