Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

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ChemPhysLett30119995_6.pdf
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1999
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Burkart, Stefan
Blessing, Nico
Klipp, Björn
Müller, Jürgen
Seifert, Gotthard
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Chemical Physics Letters. 1999, 301(5-6), pp. 546-550. Available under: doi: 10.1016/S0009-2614(98)01428-6
Zusammenfassung

Photoelectron spectra of mass-separated, negatively charged, bare and reacted aluminium clusters AlnHm− (n=12 14, m=0 2) are presented and compared to the results of corresponding calculations. A large HOMO LUMO gap of 1.4 eV is found for the neutral Al13H cluster, indicating an extraordinarily high stability of this cluster. Adsorption of a second hydrogen atom results in the disappearance of the gap.

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ISO 690BURKART, Stefan, Nico BLESSING, Björn KLIPP, Jürgen MÜLLER, Gerd GANTEFÖR, Gotthard SEIFERT, 1999. Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?. In: Chemical Physics Letters. 1999, 301(5-6), pp. 546-550. Available under: doi: 10.1016/S0009-2614(98)01428-6
BibTex
@article{Burkart1999Exper-4681,
  year={1999},
  doi={10.1016/S0009-2614(98)01428-6},
  title={Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?},
  number={5-6},
  volume={301},
  journal={Chemical Physics Letters},
  pages={546--550},
  author={Burkart, Stefan and Blessing, Nico and Klipp, Björn and Müller, Jürgen and Ganteför, Gerd and Seifert, Gotthard}
}
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