Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

Burkart, Stefan; Blessing, Nico; Klipp, Björn; Müller, Jürgen; Ganteför, Gerd; Seifert, Gotthard

Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

Files

ChemPhysLett30119995_6.pdf(296.77 KB)

Date

1999

Authors

Burkart, Stefan

Blessing, Nico

Klipp, Björn

Müller, Jürgen

Ganteför, Gerd

Seifert, Gotthard

Publication type

Journal article

Published in

Chemical Physics Letters ; 301 (1999), 5-6. - pp. 546-550

Abstract

Photoelectron spectra of mass-separated, negatively charged, bare and reacted aluminium clusters AlnHm− (n=12 14, m=0 2) are presented and compared to the results of corresponding calculations. A large HOMO LUMO gap of 1.4 eV is found for the neutral Al13H cluster, indicating an extraordinarily high stability of this cluster. Adsorption of a second hydrogen atom results in the disappearance of the gap.

Subject (DDC)

530 Physics

Cite This

ISO 690

BURKART, Stefan, Nico BLESSING, Björn KLIPP, Jürgen MÜLLER, Gerd GANTEFÖR, Gotthard SEIFERT, 1999. Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?. In: Chemical Physics Letters. 301(5-6), pp. 546-550. Available under: doi: 10.1016/S0009-2614(98)01428-6

BibTex

@article{Burkart1999Exper-4681,
  year={1999},
  doi={10.1016/S0009-2614(98)01428-6},
  title={Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?},
  number={5-6},
  volume={301},
  journal={Chemical Physics Letters},
  pages={546--550},
  author={Burkart, Stefan and Blessing, Nico and Klipp, Björn and Müller, Jürgen and Ganteför, Gerd and Seifert, Gotthard}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/4681">
    <dc:creator>Burkart, Stefan</dc:creator>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:49:32Z</dcterms:available>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:49:32Z</dc:date>
    <dc:rights>terms-of-use</dc:rights>
    <dc:contributor>Blessing, Nico</dc:contributor>
    <dcterms:bibliographicCitation>First publ. in: Chemical Physics Letters 301 (1999), 5-6, pp. 546-550</dcterms:bibliographicCitation>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4681/1/ChemPhysLett30119995_6.pdf"/>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/4681"/>
    <dc:contributor>Burkart, Stefan</dc:contributor>
    <dc:creator>Blessing, Nico</dc:creator>
    <dc:contributor>Seifert, Gotthard</dc:contributor>
    <dc:creator>Ganteför, Gerd</dc:creator>
    <dc:format>application/pdf</dc:format>
    <dc:creator>Klipp, Björn</dc:creator>
    <dcterms:abstract xml:lang="eng">Photoelectron spectra of mass-separated, negatively charged, bare and reacted aluminium clusters AlnHm− (n=12 14, m=0 2) are presented and compared to the results of corresponding calculations. A large HOMO LUMO gap of 1.4 eV is found for the neutral Al13H cluster, indicating an extraordinarily high stability of this cluster. Adsorption of a second hydrogen atom results in the disappearance of the gap.</dcterms:abstract>
    <dc:creator>Müller, Jürgen</dc:creator>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>Klipp, Björn</dc:contributor>
    <dc:language>eng</dc:language>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:contributor>Müller, Jürgen</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dc:creator>Seifert, Gotthard</dc:creator>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4681/1/ChemPhysLett30119995_6.pdf"/>
    <dcterms:issued>1999</dcterms:issued>
    <dcterms:title>Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?</dcterms:title>
  </rdf:Description>
</rdf:RDF>

Bibliography of Konstanz

No