Organometallics Meet Colloid Chemistry : A Case Study in Three Phases Based on Molecular Carbonyl Precursors Containing Zinc and Manganese

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Organometallics_Meet_Colloid_Chemistry.pdf
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2007
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Orlov, Andrey V.
Roy, Abhijit
Lehmann, Michael
Driess, Matthias
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Two organometallic compounds containing zinc and manganese in different ratios are used as single-source precursors for the preparation of various new, bimetallic oxide materials with nanoscaled dimensions. It is shown that the materials synthesis can be performed in the solid-state, the liquid-phase, and even in the gas-phase. The molecular composition of the precursors determines the composition of the resulting materials. In addition, two novel methods for the preparation of highly crystalline metal oxide colloids are presented: The coupling between a gas-phase process and a colloidal approach, and the application of ozone as an oxidant for the transformation of metal carbonyls into oxides in the liquid phase.

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ISO 690ORLOV, Andrey V., Abhijit ROY, Michael LEHMANN, Matthias DRIESS, Sebastian POLARZ, 2007. Organometallics Meet Colloid Chemistry : A Case Study in Three Phases Based on Molecular Carbonyl Precursors Containing Zinc and Manganese. In: Journal of the American Chemical Society. 2007, 129(2), pp. 371-375. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja0659626
BibTex
@article{Orlov2007Organ-10011,
  year={2007},
  doi={10.1021/ja0659626},
  title={Organometallics Meet Colloid Chemistry : A Case Study in Three Phases Based on Molecular Carbonyl Precursors Containing Zinc and Manganese},
  number={2},
  volume={129},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={371--375},
  author={Orlov, Andrey V. and Roy, Abhijit and Lehmann, Michael and Driess, Matthias and Polarz, Sebastian}
}
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