Publikation: Effect of Hydrocarbon Chain Length of Amphiphilic Ruthenium Dyes on Solid-State Dye-Sensitized Photovoltaics
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2005
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Nano Letters. 2005, 5(7), pp. 1315-1320. ISSN 1530-6984. eISSN 1530-6992. Available under: doi: 10.1021/nl050555y
Zusammenfassung
We studied the influence of the hydrophobic hydrocarbon chain length of amphiphilic ruthenium dyes on the device performance in solid-state dye-sensitized solar cells. We found that the dyes with longer hydrocarbon chains gave higher efficiency values when used as a sensitizer in solid-state dye-sensitized solar cells. With increasing chain length, we observed higher currents and open-circuit voltages up to a limiting chain length. We attribute this improvement to the expected larger distance between TiO2 and the hole conductor, which seems to suppress recombination effectively.
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SCHMIDT-MENDE, Lukas, Jessica E. KROEZE, James R. DURRANT, Mohammad Khaja NAZEERUDDIN, Michael GRÄTZEL, 2005. Effect of Hydrocarbon Chain Length of Amphiphilic Ruthenium Dyes on Solid-State Dye-Sensitized Photovoltaics. In: Nano Letters. 2005, 5(7), pp. 1315-1320. ISSN 1530-6984. eISSN 1530-6992. Available under: doi: 10.1021/nl050555yBibTex
@article{SchmidtMende2005Effec-25202,
year={2005},
doi={10.1021/nl050555y},
title={Effect of Hydrocarbon Chain Length of Amphiphilic Ruthenium Dyes on Solid-State Dye-Sensitized Photovoltaics},
number={7},
volume={5},
issn={1530-6984},
journal={Nano Letters},
pages={1315--1320},
author={Schmidt-Mende, Lukas and Kroeze, Jessica E. and Durrant, James R. and Nazeeruddin, Mohammad Khaja and Grätzel, Michael}
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<dcterms:abstract xml:lang="eng">We studied the influence of the hydrophobic hydrocarbon chain length of amphiphilic ruthenium dyes on the device performance in solid-state dye-sensitized solar cells. We found that the dyes with longer hydrocarbon chains gave higher efficiency values when used as a sensitizer in solid-state dye-sensitized solar cells. With increasing chain length, we observed higher currents and open-circuit voltages up to a limiting chain length. We attribute this improvement to the expected larger distance between TiO2 and the hole conductor, which seems to suppress recombination effectively.</dcterms:abstract>
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