Saturated polar-substituted polyethylene elastomers from insertion polymerization

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Ruenzi_270869.pdf(346.7 KB)
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2014
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urn:nbn:de:bsz:352-270869
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10.1002/adfm.201301755
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Advanced Functional Materials ; 24 (2014), 3. - pp. 387-395. - ISSN 1616-301X. - eISSN 1616-3028
Abstract
Saturated, polar-substituted elastomers consisting of a linear polyethylene backbone are prepared directly by insertion copolymerization of ethylene with polar-functionalized vinyl monomers employing functional-group tolerant catalysis. This unprecedented approach to elastomers is compatible with a wide range of different crosslinking chemistries. Crosslinking of the materials occurs efficiently, as concluded from gel contents and spectroscopic observations. Mechanical and thermal properties are revealed by dynamic mechanical analysis.
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540 Chemistry
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elastomers,crosslinking,insertion polymerization,dynamic mechanical analysis,catalysts
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ISO 690RÃœNZI, Thomas, Stefan MECKING, 2014. Saturated polar-substituted polyethylene elastomers from insertion polymerization. In: Advanced Functional Materials. 24(3), pp. 387-395. ISSN 1616-301X. eISSN 1616-3028. Available under: doi: 10.1002/adfm.201301755
BibTex
@article{Runzi2014Satur-27086,
  year={2014},
  doi={10.1002/adfm.201301755},
  title={Saturated polar-substituted polyethylene elastomers from insertion polymerization},
  number={3},
  volume={24},
  issn={1616-301X},
  journal={Advanced Functional Materials},
  pages={387--395},
  author={Rünzi, Thomas and Mecking, Stefan}
}
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