Experimentelle und theoretische Untersuchungen zur Reaktivität von Metallakumulenen

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2009
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Drexler, Matthias
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urn:nbn:de:bsz:352-opus-79760
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Experimental and theoretical studies about the reactivity of metallacumulenes
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Abstract
In the first part of this work, the reactivity of pi-donor substituted allenylidene complexes was investigated and harnessed for the generation of new carbene and allenylidene complexes.
The second part deals with the synthesis and electrochemical properties of heterobinuclear allenylidene complexes.
In the third part, transmetallation reactions of carbene and allenylidene ligands were investigated and mechanism based on density functional theory calculations are given.
Summary in another language
Im ersten Teil der Arbeit wurde die Reaktivität von pi-Donor-substituierten Allenylidenkomplexen gegenüber N-Nukleophilen untersucht und zur Synthese neuartiger Allenyliden- und Carben-Komplexe ausgenutzt.
Der zweite Teil beschäftigt sich mit der Synthese heterobinuklearer Allenylidenkomplexe und elektrochemische und dichtefunktionaltheoretische Untersuchungen zur elektronischen Kommunikation entlang des pi-Systems.
Im dritten Teil wurden experimentelle Untersuchungen zur Transmetallierung von Carben- und Allenyliden-Liganden durchgeführt und auf dichtefunktionaltheoretischen Berechnungen Mechanismen der Reaktionen vorgeschlagen.
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540 Chemistry
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allenylidene complexes,electrochemistry,synthesis,DFT calculations,reactivity
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ISO 690DREXLER, Matthias, 2009. Experimentelle und theoretische Untersuchungen zur Reaktivität von Metallakumulenen [Dissertation]. Konstanz: University of Konstanz
BibTex
@phdthesis{Drexler2009Exper-9887,
  year={2009},
  title={Experimentelle und theoretische Untersuchungen zur Reaktivität von Metallakumulenen},
  author={Drexler, Matthias},
  address={Konstanz},
  school={Universität Konstanz}
}
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April 17, 2009
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