Catalytic Isomerizing ω-Functionalization of Fatty Acids
Catalytic Isomerizing ω-Functionalization of Fatty Acids
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2015
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ACS Catalysis ; 5 (2015), 10. - pp. 5951-5972. - eISSN 2155-5435
Abstract
Isomerizing functionalization reactions that convert the internal double bonds of unsaturated fatty acids from plant or algae oils to a terminal functional group are attractive because they can generate linear long-chain α,ω-difunctional compounds that incorporate the entire length of the substrates chain. The state of the art toward this formidable synthetic challenge via different catalytic approaches, namely isomerizing borylations, silylations, and carbonylations (and for comparison, olefin metathesis) is reviewed comprehensively and analyzed with regard to underlying mechanistic principles, performance, practicability, and scope.
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540 Chemistry
Keywords
isomerizing functionalization, transition metal catalysis, fatty acids, hydroformylation, hydroboration, silylation, alkoxycarbonylation, olefin metathesis
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GOLDBACH, Verena, Philipp ROESLE, Stefan MECKING, 2015. Catalytic Isomerizing ω-Functionalization of Fatty Acids. In: ACS Catalysis. 5(10), pp. 5951-5972. eISSN 2155-5435. Available under: doi: 10.1021/acscatal.5b01508BibTex
@article{Goldbach2015Catal-32089, year={2015}, doi={10.1021/acscatal.5b01508}, title={Catalytic Isomerizing ω-Functionalization of Fatty Acids}, number={10}, volume={5}, journal={ACS Catalysis}, pages={5951--5972}, author={Goldbach, Verena and Roesle, Philipp and Mecking, Stefan} }
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