Catalytic Isomerizing ω-Functionalization of Fatty Acids

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2015
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ACS Catalysis. 2015, 5(10), pp. 5951-5972. eISSN 2155-5435. Available under: doi: 10.1021/acscatal.5b01508
Zusammenfassung

Isomerizing functionalization reactions that convert the internal double bonds of unsaturated fatty acids from plant or algae oils to a terminal functional group are attractive because they can generate linear long-chain α,ω-difunctional compounds that incorporate the entire length of the substrates chain. The state of the art toward this formidable synthetic challenge via different catalytic approaches, namely isomerizing borylations, silylations, and carbonylations (and for comparison, olefin metathesis) is reviewed comprehensively and analyzed with regard to underlying mechanistic principles, performance, practicability, and scope.

Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
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isomerizing functionalization, transition metal catalysis, fatty acids, hydroformylation, hydroboration, silylation, alkoxycarbonylation, olefin metathesis
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Zitieren
ISO 690GOLDBACH, Verena, Philipp ROESLE, Stefan MECKING, 2015. Catalytic Isomerizing ω-Functionalization of Fatty Acids. In: ACS Catalysis. 2015, 5(10), pp. 5951-5972. eISSN 2155-5435. Available under: doi: 10.1021/acscatal.5b01508
BibTex
@article{Goldbach2015Catal-32089,
  year={2015},
  doi={10.1021/acscatal.5b01508},
  title={Catalytic Isomerizing ω-Functionalization of Fatty Acids},
  number={10},
  volume={5},
  journal={ACS Catalysis},
  pages={5951--5972},
  author={Goldbach, Verena and Roesle, Philipp and Mecking, Stefan}
}
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