Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides : structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

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2021
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Nimax, Patrick R.
Zoller, Florian
Blockhaus, Tobias
Wagner, Fritz
Fattakhova, Dina
Sünkel, Karlheinz
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Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(I) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.

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ISO 690NIMAX, Patrick R., Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA, Karlheinz SÜNKEL, 2021. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides : structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. In: Dalton Transactions. Royal Society of Chemistry (RSC). 2021, 50(47), pp. 17643-17652. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/D1DT02866A
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@article{Nimax2021Coord-55814,
  year={2021},
  doi={10.1039/D1DT02866A},
  title={Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides : structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide},
  number={47},
  volume={50},
  issn={1477-9226},
  journal={Dalton Transactions},
  pages={17643--17652},
  author={Nimax, Patrick R. and Rotthowe, Nils and Zoller, Florian and Blockhaus, Tobias and Wagner, Fritz and Fattakhova, Dina and Sünkel, Karlheinz}
}
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