Indication of a size-dependent transition from molecular to dissociative chemisorption on clusters

Burkart, Stefan; Blessing, Nico; Ganteför, Gerd

Indication of a size-dependent transition from molecular to dissociative chemisorption on clusters

Dateien

PhysRevB60199923.pdfGröße: 125.38 KBDownloads: 278

Datum

1999

Autor:innen

Burkart, Stefan

Blessing, Nico

Ganteför, Gerd

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Physik

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Physical Review / B. 1999, 60(23), pp. 15639-15642. Available under: doi: 10.1103/PhysRevB.60.15639

Zusammenfassung

We report experimental indications for a size-dependent change of the chemical nature of chemisorption on small atomic clusters. We studied chemisorption of atomic hydrogen on negatively charged Tin- clusters using mass and photoelectron spectroscopy. Our experimental data support the assumption that for clusters with up to four Ti atoms, adsorption of intact H2 molecules is the energetically preferred configuration. For larger Tin clusters with n>4, dissociative hydrogen chemisorption is the most stable configuration, forming clusters with an electronic structure similar to bulk TiH2.

Fachgebiet (DDC)

530 Physik

Zitieren

ISO 690

BURKART, Stefan, Nico BLESSING, Gerd GANTEFÖR, 1999. Indication of a size-dependent transition from molecular to dissociative chemisorption on clusters. In: Physical Review / B. 1999, 60(23), pp. 15639-15642. Available under: doi: 10.1103/PhysRevB.60.15639

BibTex

@article{Burkart1999Indic-4756,
  year={1999},
  doi={10.1103/PhysRevB.60.15639},
  title={Indication of a size-dependent transition from molecular to dissociative chemisorption on clusters},
  number={23},
  volume={60},
  journal={Physical Review / B},
  pages={15639--15642},
  author={Burkart, Stefan and Blessing, Nico and Ganteför, Gerd}
}

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