Publikation: AlH3 and Al2H6 : magic clusters with unmagical properties
Lade...
Dateien
Datum
2001
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Physical Review Letters. 2001, 86(4), pp. 692-695. Available under: doi: 10.17877/DE290R-12122
Zusammenfassung
Enhanced stability, low electron affinity, and high ionization potential are the hallmarks of a magic cluster. With an electron affinity of 0.28 eV, ionization potential of 11.43 eV, and a large binding energy, AlH3 satisfies these criteria. However, unlike other magic clusters that interact only weakly with each other, two AlH3 clusters bind to each other with an energy of 1.54 eV. The resulting Al2H6, while also a magic cluster in its own right, possesses the most unusual property that the difference between its adiabatic and vertical detachment energy is about 2 eV the largest of any known cluster. These results, based on density functional theory, are verified experimentally through photodetachment spectroscopy.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
530 Physik
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
RAO, Bijan K., Purusottam JENA, Stefan BURKART, Gerd GANTEFÖR, Gotthard SEIFERT, 2001. AlH3 and Al2H6 : magic clusters with unmagical properties. In: Physical Review Letters. 2001, 86(4), pp. 692-695. Available under: doi: 10.17877/DE290R-12122BibTex
@article{Rao2001Al2H6-4771,
year={2001},
doi={10.17877/DE290R-12122},
title={AlH3 and Al2H6 : magic clusters with unmagical properties},
number={4},
volume={86},
journal={Physical Review Letters},
pages={692--695},
author={Rao, Bijan K. and Jena, Purusottam and Burkart, Stefan and Ganteför, Gerd and Seifert, Gotthard}
}RDF
<rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/4771">
<dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4771/1/PhysRevLett862001.pdf"/>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:50:13Z</dcterms:available>
<dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4771/1/PhysRevLett862001.pdf"/>
<dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
<dcterms:bibliographicCitation>First publ. in: Physical Review Letters 86 (2001), 4, pp. 692 - 695</dcterms:bibliographicCitation>
<dc:contributor>Ganteför, Gerd</dc:contributor>
<dc:creator>Ganteför, Gerd</dc:creator>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:50:13Z</dc:date>
<dcterms:title>AlH3 and Al2H6 : magic clusters with unmagical properties</dcterms:title>
<dc:contributor>Burkart, Stefan</dc:contributor>
<dc:creator>Burkart, Stefan</dc:creator>
<dc:contributor>Seifert, Gotthard</dc:contributor>
<dc:contributor>Jena, Purusottam</dc:contributor>
<dcterms:abstract xml:lang="eng">Enhanced stability, low electron affinity, and high ionization potential are the hallmarks of a magic cluster. With an electron affinity of 0.28 eV, ionization potential of 11.43 eV, and a large binding energy, AlH3 satisfies these criteria. However, unlike other magic clusters that interact only weakly with each other, two AlH3 clusters bind to each other with an energy of 1.54 eV. The resulting Al2H6, while also a magic cluster in its own right, possesses the most unusual property that the difference between its adiabatic and vertical detachment energy is about 2 eV the largest of any known cluster. These results, based on density functional theory, are verified experimentally through photodetachment spectroscopy.</dcterms:abstract>
<dc:rights>terms-of-use</dc:rights>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
<dc:creator>Jena, Purusottam</dc:creator>
<dcterms:issued>2001</dcterms:issued>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/4771"/>
<dc:contributor>Rao, Bijan K.</dc:contributor>
<dc:language>eng</dc:language>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dc:creator>Rao, Bijan K.</dc:creator>
<dc:format>application/pdf</dc:format>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
<dc:creator>Seifert, Gotthard</dc:creator>
</rdf:Description>
</rdf:RDF>Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Nein
