@article{Lorbach2011-11diffe-39281,
  year={2011},
  doi={10.1016/j.ica.2011.07.050},
  title={The difference regarding the reactivity of the silanides Na[SitBu<sub>3</sub>] and Na[SiPhtBu<sub>2</sub>] towards white phosphorus},
  number={1},
  volume={378},
  issn={0020-1693},
  journal={Inorganica Chimica Acta},
  pages={1--9},
  author={Lorbach, Andreas and Breitung, Sven and Sänger, Inge and Schödel, Frauke and Bolte, Michael and Wagner, Matthias and Lerner, Hans-Wolfram}
}

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    <dc:contributor>Lerner, Hans-Wolfram</dc:contributor>
    <dc:contributor>Lorbach, Andreas</dc:contributor>
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    <dc:creator>Bolte, Michael</dc:creator>
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    <dcterms:title>The difference regarding the reactivity of the silanides Na[SitBu&lt;sub&gt;3&lt;/sub&gt;] and Na[SiPhtBu&lt;sub&gt;2&lt;/sub&gt;] towards white phosphorus</dcterms:title>
    <dc:creator>Lorbach, Andreas</dc:creator>
    <dc:creator>Wagner, Matthias</dc:creator>
    <dc:contributor>Schödel, Frauke</dc:contributor>
    <dc:creator>Schödel, Frauke</dc:creator>
    <dc:creator>Lerner, Hans-Wolfram</dc:creator>
    <dc:contributor>Bolte, Michael</dc:contributor>
    <dc:creator>Breitung, Sven</dc:creator>
    <dcterms:issued>2011-11</dcterms:issued>
    <dc:contributor>Wagner, Matthias</dc:contributor>
    <dcterms:abstract xml:lang="eng">The sodium tetraphosphenediides Na&lt;sub&gt;2&lt;/sub&gt;[tBu&lt;sub&gt;2&lt;/sub&gt;RSiP–P=P–PSiRtBu&lt;sub&gt;2&lt;/sub&gt;] (R = tBu, Ph) were formed when P&lt;sub&gt;4&lt;/sub&gt; was treated with two equivalents of the silanides Na[SiRtBu&lt;sub&gt;2&lt;/sub&gt;] in thf. Whereas treatment of P&lt;sub&gt;4&lt;/sub&gt; with three equivalents of Na[SiPhtBu&lt;sub&gt;2&lt;/sub&gt;] in thf gave the tetraphosphide Na&lt;sub&gt;3&lt;/sub&gt;[P(PSiPhtBu&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;] as main product (along with, e.g., Na&lt;sub&gt;2&lt;/sub&gt;[PSiPhtBu&lt;sub&gt;2&lt;/sub&gt;], Na&lt;sub&gt;2&lt;/sub&gt;[tBu&lt;sub&gt;2&lt;/sub&gt;PhSiP–P=P–PSiPhtBu&lt;sub&gt;2&lt;/sub&gt;], and Na&lt;sub&gt;2&lt;/sub&gt;[P&lt;sub&gt;5&lt;/sub&gt;(SiPhtBu&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;]). However, no tetraphosphide Na&lt;sub&gt;3&lt;/sub&gt;[P(PSitBu&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;] was formed by the reaction of P&lt;sub&gt;4&lt;/sub&gt; with three equivalents of Na[SitBu&lt;sub&gt;3&lt;/sub&gt;] in thf. The triphosphide Na[tBu&lt;sub&gt;2&lt;/sub&gt;PhSiP–P=PSiPhtBu&lt;sub&gt;2&lt;/sub&gt;] could be obtained together with Na[PHSiPhtBu&lt;sub&gt;2&lt;/sub&gt;] by protolysis of Na&lt;sub&gt;3&lt;/sub&gt;[P(PSiPhtBu&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;]. When a mixture of a 3:1 reaction of Na[SiPhtBu&lt;sub&gt;2&lt;/sub&gt;] and P4 was heated to 100 °C in vacuo, {Na[P(SiPhtBu2)2]}2 was generated along with Na2[PSiPhtBu2] and P&lt;sub&gt;4&lt;/sub&gt;. Single crystals of Na[P(SiPhtBu&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;] were grown from a heptane solution at room temperature (monoclinic space group C2/c).</dcterms:abstract>
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    <dc:contributor>Breitung, Sven</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-06-14T09:53:28Z</dc:date>
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    <dc:creator>Sänger, Inge</dc:creator>
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