AlH3 and Al2H6 : magic clusters with unmagical properties
| Type of Publication: | Journal article |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-87229 |
| Author: | Rao, Bijan K.; Jena, Purusottam; Burkart, Stefan; Ganteför, Gerd; Seifert, Gotthard |
| Year of publication: | 2001 |
| Published in: | Physical Review Letters ; 86 (2001), 4. - pp. 692-695 |
| DOI (citable link): | https://dx.doi.org/10.17877/DE290R-12122 |
| Summary: |
Enhanced stability, low electron affinity, and high ionization potential are the hallmarks of a magic cluster. With an electron affinity of 0.28 eV, ionization potential of 11.43 eV, and a large binding energy, AlH3 satisfies these criteria. However, unlike other magic clusters that interact only weakly with each other, two AlH3 clusters bind to each other with an energy of 1.54 eV. The resulting Al2H6, while also a magic cluster in its own right, possesses the most unusual property that the difference between its adiabatic and vertical detachment energy is about 2 eV the largest of any known cluster. These results, based on density functional theory, are verified experimentally through photodetachment spectroscopy.
|
| PACS Classification: | 73.22.-f; 31.15.Ar; 71.15.Nc |
| Subject (DDC): | 530 Physics |
| Link to License: | In Copyright |
Cite This
Files in this item
![[PDF]](/themes/Kops/images/mimes/pdf.png "PDF file"){kind=small}
RAO, Bijan K., Purusottam JENA, Stefan BURKART, Gerd GANTEFÖR, Gotthard SEIFERT, 2001. AlH3 and Al2H6 : magic clusters with unmagical properties. In: Physical Review Letters. 86(4), pp. 692-695. Available under: doi: 10.17877/DE290R-12122
@article{Rao2001Al2H6-4771, title={AlH3 and Al2H6 : magic clusters with unmagical properties}, year={2001}, doi={10.17877/DE290R-12122}, number={4}, volume={86}, journal={Physical Review Letters}, pages={692--695}, author={Rao, Bijan K. and Jena, Purusottam and Burkart, Stefan and Ganteför, Gerd and Seifert, Gotthard} }
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/4771"> <dc:contributor>Rao, Bijan K.</dc:contributor> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4771/1/PhysRevLett862001.pdf"/> <dcterms:abstract xml:lang="eng">Enhanced stability, low electron affinity, and high ionization potential are the hallmarks of a magic cluster. With an electron affinity of 0.28 eV, ionization potential of 11.43 eV, and a large binding energy, AlH3 satisfies these criteria. However, unlike other magic clusters that interact only weakly with each other, two AlH3 clusters bind to each other with an energy of 1.54 eV. The resulting Al2H6, while also a magic cluster in its own right, possesses the most unusual property that the difference between its adiabatic and vertical detachment energy is about 2 eV the largest of any known cluster. These results, based on density functional theory, are verified experimentally through photodetachment spectroscopy.</dcterms:abstract> <dc:creator>Rao, Bijan K.</dc:creator> <dc:contributor>Seifert, Gotthard</dc:contributor> <dc:contributor>Ganteför, Gerd</dc:contributor> <dc:contributor>Jena, Purusottam</dc:contributor> <dc:rights>terms-of-use</dc:rights> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/41"/> <dcterms:bibliographicCitation>First publ. in: Physical Review Letters 86 (2001), 4, pp. 692 - 695</dcterms:bibliographicCitation> <dcterms:issued>2001</dcterms:issued> <dc:creator>Burkart, Stefan</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:50:13Z</dcterms:available> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:50:13Z</dc:date> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:contributor>Burkart, Stefan</dc:contributor> <dc:creator>Jena, Purusottam</dc:creator> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:creator>Ganteför, Gerd</dc:creator> <dc:language>eng</dc:language> <dc:creator>Seifert, Gotthard</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/4771"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4771/1/PhysRevLett862001.pdf"/> <dc:format>application/pdf</dc:format> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/41"/> <dcterms:title>AlH3 and Al2H6 : magic clusters with unmagical properties</dcterms:title> </rdf:Description> </rdf:RDF>
Downloads since Oct 1, 2014 (Information about access statistics)
| PhysRevLett862001.pdf | 535 |
This item appears in the following Collection(s)
Search KOPS
Browse
My Account
