Adsorption and Decomposition of DMMP on Size‐Selected (WO<sub>3</sub>)<sub>3</sub> Clusters
| Type of Publication: | Journal article |
| Publication status: | Published |
| Author: | Tang, Xin; Hicks, Zachary; Ganteför, Gerd; Eichhorn, Bryan W.; Bowen, Kit H. |
| Year of publication: | 2018 |
| Published in: | ChemistrySelect ; 3 (2018), 13. - pp. 3718-3721. - eISSN 2365-6549 |
| DOI (citable link): | https://dx.doi.org/10.1002/slct.201800229 |
| Summary: |
The adsorption and decomposition behaviors of dimethyl methylphosphate (DMMP) on size‐selected (WO3)3 clusters were studied by a combination of X‐ray Photoelectron Spectroscopy (XPS) and Temperature Programmed Reaction (TPR). The fate of DMMP adsorbed on (WO3)3 clusters was found to be very similar to its fate on (MoO3)3. In contrast to DMMP on (MoO3)3, however, dimethyl ether was observed as a product in the reaction of DMMP with (WO3)3, in addition to methanol, due to the higher Lewis acidity of (WO3)3 clusters as compared to (MoO3)3.
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| Subject (DDC): | 530 Physics |
| Bibliography of Konstanz: | Yes |
| Refereed: | Yes |
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TANG, Xin, Zachary HICKS, Gerd GANTEFÖR, Bryan W. EICHHORN, Kit H. BOWEN, 2018. Adsorption and Decomposition of DMMP on Size‐Selected (WO3)3 Clusters. In: ChemistrySelect. 3(13), pp. 3718-3721. eISSN 2365-6549. Available under: doi: 10.1002/slct.201800229
@article{Tang2018-04-09Adsor-42300, title={Adsorption and Decomposition of DMMP on Size‐Selected (WO3)3 Clusters}, year={2018}, doi={10.1002/slct.201800229}, number={13}, volume={3}, journal={ChemistrySelect}, pages={3718--3721}, author={Tang, Xin and Hicks, Zachary and Ganteför, Gerd and Eichhorn, Bryan W. and Bowen, Kit H.} }
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