KOPS - The Institutional Repository of the University of Konstanz

ansa-metallocene derivatives : XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction

ansa-metallocene derivatives : XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction

Type of Publication: Journal article
URI (citable link): http://nbn-resolving.de/urn:nbn:de:bsz:352-239452
Author: Burger, Peter; Brintzinger, Hans-Herbert
Year of publication: 1991
Published in: Journal of Organometallic Chemistry ; 407 (1991), 2. - pp. 207-213. - ISSN 0022-328X
DOI (citable link): https://dx.doi.org/10.1016/0022-328X(91)86118-A
Summary:
Novel olefin-linked biscyclopentadienyl ligands have been prepared by McMurry coupling reactions of benzoyl- and acetyl-cyclopentadienyl sodium. Reactions of the disodium salts with TiCl4 or TiCl3 · 3THF afford the alkene-bridged ansa-titanocene dichlorides. 13C-NMR shifts to the bridge carbon atoms do not indicate any interaction between the olefin π-system and the metal.
Subject (DDC): 540 Chemistry
Link to License: In Copyright

Cite This

Files in this item

[PDF]
Name: Burger_239452.pdf
Size: 270 KiB
Format: PDF
View/Open
Checksum: MD5:1d38a4ba9811f58100f5665fd885f849

BURGER, Peter, Hans-Herbert BRINTZINGER, 1991. ansa-metallocene derivatives : XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction. In: Journal of Organometallic Chemistry. 407(2), pp. 207-213. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(91)86118-A

@article{Burger1991ansam-23945, title={ansa-metallocene derivatives : XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction}, year={1991}, doi={10.1016/0022-328X(91)86118-A}, number={2}, volume={407}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={207--213}, author={Burger, Peter and Brintzinger, Hans-Herbert} }

eng 2013-08-08T06:37:24Z Journal of Organometallic Chemistry ; 407 (1991), 2. - S. 207-213 2013-08-08T06:37:24Z ansa-metallocene derivatives : XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction Burger, Peter Novel olefin-linked biscyclopentadienyl ligands have been prepared by McMurry coupling reactions of benzoyl- and acetyl-cyclopentadienyl sodium. Reactions of the disodium salts with TiCl<sub>4</sub> or TiCl<sub>3</sub> · 3THF afford the alkene-bridged ansa-titanocene dichlorides. <sup>13</sup>C-NMR shifts to the bridge carbon atoms do not indicate any interaction between the olefin π-system and the metal. terms-of-use Burger, Peter 1991 Brintzinger, Hans-Herbert Brintzinger, Hans-Herbert

Downloads since Oct 1, 2014 (Information about access statistics)

Burger_239452.pdf 172

This item appears in the following Collection(s)

Search KOPS


Browse

My Account